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Thallium trinitrate mediated ring contraction of monocyclic ketones: Stereochemical aspects

โœ Scribed by Helena M.C. Ferraz; Luiz F. Silva Jr.

Book ID
104256617
Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
180 KB
Volume
38
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

The reaction of 3-and 4-aikylcyclohexanones with thallium trinitrate (TTN) leads to the

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ChemInform Abstract: Thallium Trinitrate
ChemInform Abstract: Thallium Trinitrate Mediated Ring Contraction of Monocyclic Ketones: Stereochemical Aspects.
โœ H. M. C. FERRAZ; L. F. JUN. SILVA ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 29 KB

Thallium Trinitrate Mediated Ring Contraction of Monocyclic Ketones: Stereochemical Aspects. -Treatment of alkylcyclohexanones (I) or (IV) with thallium(III) nitrate induces ring contractions to cyclopentanecarboxylic acids (II), (III), and (V), with high degree of stereoselectivity and regioselect