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Thallium Trinitrate Mediated Oxidation of 3-Alkenols: Ring Contraction vs Cyclization.

✍ Scribed by Helena M. C. Ferraz; Luiz S. Longo Jr.; Julio Zukerman-Schpector

Book ID
101930166
Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
33
Category
Article
ISSN
0931-7597

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Thallium Trinitrate Mediated Ring Contraction of Monocyclic Ketones: Stereochemical Aspects. -Treatment of alkylcyclohexanones (I) or (IV) with thallium(III) nitrate induces ring contractions to cyclopentanecarboxylic acids (II), (III), and (V), with high degree of stereoselectivity and regioselect