TG and DSC studies of the surface reaction of γ-Al2O2 with Cl2
✍ Scribed by F Réti; I Bertóti; G Mink; I.S Pap
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 257 KB
- Volume
- 107
- Category
- Article
- ISSN
- 0040-6031
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The reactions of C1 and Br atoms with HzOz have been studied in the range of 300-350 K using the very-low-pressure-reactor technique. It was found that metathesis to produce HX and H02 is the only significant process (199%). For the reaction of Br 2 Br + HzO2 + HBr + HOz k z (300 K) = 1.3 f 0.45 X a
Rate constants for the reaction of CN( u= 0) with Cl,, FZ and O2 have been measured. CN radicals were generated by photolysis of C2Nz with pulsed radiation at 193 nm. Laser-induced fluorescence (LIF) was used to monitor the decay profiles of CN radical concentrations. The valuesobtainedare: k(CN/CI?