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Tetrathiafulvalenes as π-Electron Donors for Intramolecular Charge-Transfer Materials

✍ Scribed by Martin R. Bryce

Publisher: John Wiley and Sons
Year: 1999
Tongue: English
Weight: 355 KB
Volume: 11
Category: Article
ISSN: 0935-9648
DOI: 10.1002/(sici)1521-4095(199901)11:1<11::aid-adma11>3.0.co;2-3

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Dimethyl[2,4-dioxo(1H,3H)pyrimido ]tetrathiafulvalene (1) and dimethyl-[2-amino-4oxo(3H)pyrimido ]tetrathiafulvalene (4) form unusual inner salts by oxidation in the presence of bases. The insoluble black -green betaines 2 and 5 react with acids to form cation radical salts. Betaine 2 in the presenc