Dioxo- and aminooxopyrimidotetrathiafulvalenes: π-electron donors for design of conducting materials containing intramolecular hydrogen bonds of nucleic acid base pair type

Dioxo- and aminooxopyrimidotetrathiafulv

Dioxo- and aminooxopyrimidotetrathiafulvalenes: π-Electron donors for design of conducting materials containing intramolecular hydrogen bonds of nucleic acid base pair type

✍ O. Neilands; V. Tilika; I. Sudmale; I. Grigorjeva; A. Edzina; E. Fonavs; I. Muzi 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 417 KB 👁 1 views

Dimethyl[2,4-dioxo(1H,3H)pyrimido ]tetrathiafulvalene (1) and dimethyl-[2-amino-4oxo(3H)pyrimido ]tetrathiafulvalene (4) form unusual inner salts by oxidation in the presence of bases. The insoluble black -green betaines 2 and 5 react with acids to form cation radical salts. Betaine 2 in the presenc