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Tetrathiafulvalene-annulated [28]hexaphyrin(1.1.1.1.1.1): a multi-electron donor system subject to conformational control

โœ Scribed by Jana, Atanu; Ishida, Masatoshi; Cho, Kevin; Ghosh, Sudip Kumar; Kwak, Kyuju; Ohkubo, Kei; Sung, Young Mo; Davis, Christina M.; Lynch, Vincent M.; Lee, Dongil; Fukuzumi, Shunichi; Kim, Dongho; Sessler, Jonathan L.


Book ID
120809138
Publisher
Royal Society of Chemistry
Year
2013
Tongue
English
Weight
964 KB
Volume
49
Category
Article
ISSN
1359-7345

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Tetrathiafulvalene (TTF) fused to acenap
โœ Martin R. Bryce; Alexander K. Lay; Andrei S. Batsanov; Judith A.K. Howard ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 210 KB

The reaction of transient 1,3-dithiole-2,4,5-trithioue 4 with acenaphthylene afforded the Diels-Alder adduct 5, which was dehydrogenated to yield 6; cross-coupling of 6 with 7 gave the tetrathiafulvalene (TIT) derivative 8, which was converted into the di(methylsulfanyl) analogue 10, the solution el