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Tetra­pyridinium α-dodeca­molybdosilicate hemihydrate

✍ Scribed by Dang, Dong-Bin ;Jin, Ya-Nan

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
346 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, (C~5~H~6~N)~4~[SiMo~12~O~40~]·0.5H~2~O, was synthesized by a hydrothermal method. The compound consists of a Keggin anion, [SiMo~12~O~40~]^4−^, disordered about a crystallographic centre of inversion, pyridinium cations, and a water molecule lying on a mirror plane. The [SiMo~12~O~40~]^4−^ anions and water molecules lie in layers, and the pyridinium cations lie between these layers, forming N—H...O and C—H...O contacts to the O atoms of [SiMo~12~O~40~]^4−^.

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