The title compound, (C~5~H~6~N)~4~[SiMo~12~O~40~]·0.5H~2~O, was synthesized by a hydrothermal method. The compound consists of a Keggin anion, [SiMo~12~O~40~]^4−^, disordered about a crystallographic centre of inversion, pyridinium cations, and a water molecule lying on a mirror plane. The [SiMo~12~
✦ LIBER ✦
Tetrakis(1,4-dimethylpyridinium) dodecamolybdosilicate
✍ Scribed by Tan, Xue-Jie ;Sun, Si-Xiu ;Liu, Lian-Dong ;Ma, Jian-Ping ;Xing, Dian-Xiang
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 673 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The anion of the title compound, (C 7 H 10 N) 4 [SiMo 12 O 40 ], has a disordered centrosymmetric 'pseudo-Keggin' structure and neighboring anions are linked into a layered structure via weak C-HÁ Á ÁO hydrogen bonding involving the DMP cations.
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