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Tetra­kis(1,4-dimethyl­pyridinium) dodeca­molybdosilicate

✍ Scribed by Tan, Xue-Jie ;Sun, Si-Xiu ;Liu, Lian-Dong ;Ma, Jian-Ping ;Xing, Dian-Xiang


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
673 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis


The anion of the title compound, (C 7 H 10 N) 4 [SiMo 12 O 40 ], has a disordered centrosymmetric 'pseudo-Keggin' structure and neighboring anions are linked into a layered structure via weak C-HÁ Á ÁO hydrogen bonding involving the DMP cations.


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Tetra­pyridinium α-dodeca­molybdosilicat
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The title compound, (C~5~H~6~N)~4~[SiMo~12~O~40~]·0.5H~2~O, was synthesized by a hydrothermal method. The compound consists of a Keggin anion, [SiMo~12~O~40~]^4−^, disordered about a crystallographic centre of inversion, pyridinium cations, and a water molecule lying on a mirror plane. The [SiMo~12~

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