𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Tetra­propyl­ammonium trans-diamminetetra­nitro­cobaltate(III)

✍ Scribed by Vermani, Bal Krishan ;Sharma, Raj Pal ;Gill, Dip Singh ;Pretto, Loretta ;Ferretti, Valeria

Book ID
104487734
Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
307 KB
Volume
62
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

The Co III title complex, [(C 3 H 7 ) 4 N][trans-Co(NH 3 ) 2 (NO 2 ) 4 ], has been synthesized and crystallized from an acetone-water mixture. The asymmetric unit contains two cations and two anions. The X-ray structure determination revealed the presence of discrete ions interacting through weak hydrogen bonds and van der Waals interactions, as well as Coulombic interactions.

metal-organic papers m2414 Vermani et al. (C 12 H 28 N)[Co(NO 2 ) 4 (NH 3 ) 2 ]

📜 SIMILAR VOLUMES

Nitro(α,β,γ,δ-tetra­phenyl­porphyrinato)
Nitro(α,β,γ,δ-tetra­phenyl­porphyrinato)­cobalt(III) benzene solvate
✍ Ohba, Shigeru ;Seki, Hiroshi 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 388 KB

In the crystal structure of the title compound, [Co(C 44 H 28 N 4 )-(NO 2 )]ÁC 6 H 6 , the Co III atom has a distorted square±pyramidal coordination, with the nitro ligand at the apical position. The CoÐN(nitro) bond distance is 1.880 (3) A Ê .

(Ethanol-O)­nitro(α,β,γ,δ-tetra­phenyl­p
(Ethanol-O)­nitro(α,β,γ,δ-tetra­phenyl­porphyrinato)­cobalt(III)
✍ Ohba, Shigeru ;Seki, Hiroshi 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 323 KB

Single-crystal X-ray study T = 297 K Mean '(C±C) = 0.004 A Ê H-atom completeness 83% Disorder in main residue R factor = 0.039 wR factor = 0.112 Data-to-parameter ratio = 15.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.