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Tetrapotassium μ-carbonato-μ-oxo-bis[nitrilotriacetatoiron(III)] dimethanol dihydrate

✍ Scribed by Fujita, T. ;Ohba, S. ;Nishida, Y. ;Goto, A. ;Tokii, T.


Book ID
114510642
Publisher
International Union of Crystallography
Year
1994
Tongue
English
Weight
332 KB
Volume
50
Category
Article
ISSN
0108-2701

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✍ Fischer, Andreas 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 288 KB

The title compound, [Eu 2 (H 2 I 2 O 10 )(H 2 O) 6 ](ClO 4 ) 2 Á2H 2 O, is isostructural with the corresponding Pr, Sm and Gd phases. It features Eu 3+ cations, which are coordinated by centrosymmetric H 2 I 2 O 10 4À anions and water molecules, forming positively charged sheets, separated by perchl