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Tetra­phenyl­phospho­nium aqua­tetra­cyano­nitridorhenate(V) penta­hydrate

✍ Scribed by Mtshali, Thato N. ;Purcell, Walter ;Visser, Hendrik G.

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
170 KB
Volume
63
Category
Article
ISSN
1600-5368

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The title compound, (C~24~H~20~P)[Re(C~10~H~9~N~3~O~2~S)O], contains well separated square-pyramidal [ORe__L__]^−^ complex anions (__L__ is the deprotonated __N__-(2-aminophenyl)-2-(mercaptomethylcarbonylamino)ethanamide ligand) and tetrahedral [(C~6~H~5~)~4~P]^+^ cations. In the anion, the Re=O bon

Tetra­phenyl­phospho­nium [2-(mercaptome
Tetra­phenyl­phospho­nium [2-(mercaptomethyl­carbonyl­amino)-N-(2-methylamino­phen­yl)ethanamido­(4−)-κ4S,N,N′,N′′]oxorhenate(V)
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The title compound, (C~24~H~20~P)[Re(C~11~H~11~N~3~O~2~S)O], is the [(C~6~H~5~)~4~P]^+^ salt of a square-pyramidal [ReO__L__]^−^ complex anion [__L__ is the deprotonated 2-(mercaptomethylcarbonylamino)-__N__-(2-methylaminophenyl)ethanamide ligand], in which the Re=O bond is apical and the tetradenta