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Tetra­phenyl­phospho­nium [2-(mercaptomethyl­carbonyl­amino)-N-(2-methylamino­phen­yl)ethanamido­(4−)-κ4S,N,N′,N′′]oxorhenate(V)

✍ Scribed by Le Gal, Julien ;Benoist, Éric ;Gressier, Marie ;Bélanger-Gariépy, Francine ;Beauchamp, André L.

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
129 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, (C~24~H~20~P)[Re(C~11~H~11~N~3~O~2~S)O], is the [(C~6~H~5~)~4~P]^+^ salt of a square-pyramidal [ReO__L__]^−^ complex anion [L is the deprotonated 2-(mercaptomethylcarbonylamino)-N-(2-methylaminophenyl)ethanamide ligand], in which the Re=O bond is apical and the tetradentate (N—N—N—S)^4−^ ligand fills the four basal sites. The presence of a methyl group on the terminal N-atom donor induces a small displacement of the coordinated S atom.

📜 SIMILAR VOLUMES

Tetra­phenyl­phospho­nium [N-(2-amino­ph
Tetra­phenyl­phospho­nium [N-(2-amino­phenyl)-2-(mercaptomethyl­carbonyl­amino)ethanamido(4−)-κ4S,N,N′,N′′]oxorhenate(V)
✍ Le Gal, Julien ;Benoist, Éric ;Gressier, Marie ;Bélanger-Gariépy, Francine ;Beau 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 125 KB

The title compound, (C~24~H~20~P)[Re(C~10~H~9~N~3~O~2~S)O], contains well separated square-pyramidal [ORe__L__]^−^ complex anions (__L__ is the deprotonated __N__-(2-aminophenyl)-2-(mercaptomethylcarbonylamino)ethanamide ligand) and tetrahedral [(C~6~H~5~)~4~P]^+^ cations. In the anion, the Re=O bon

Sodium [2-(mercaptomethyl­carbonyl­amino
Sodium [2-(mercaptomethyl­carbonyl­amino)-N-(2-mercaptophen­yl)ethanamide­(4−)-κ4S,N,N′,S′]oxorhenate(V) monohydrate
✍ Le Gal, Julien ;Benoist, Éric ;Gressier, Marie ;Bélanger-Gariépy, Francine ;Beau 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 207 KB

In the complex anion of the title compound, Na[Re(C~10~H~8~N~2~O~2~S~2~)O]·H~2~O, the Re atom adopts a square-pyramidal coordination, in which the Re=O bond is apical and the __S__,__N__,__N__,__S__-tetradentate ligand spans the four basal sites. The Na^+^ counter-ion is octahedrally surrounded by o

mer-Bis(2,3-dimeth­yl-5-oxo-1-phen­yl-2,
mer-Bis(2,3-dimeth­yl-5-oxo-1-phen­yl-2,5-dihydro-1H-pyrazole-4-carbaldehyde 4,4-dimethyl­thio­semicarbazonato-κ3S,N,O)cobalt(III) tetra­fluoro­borate
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