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Tetraphenylantimony(V) O,O′-dialkyl dithiophosphates [Sb(C6H5)4{S2P(OR)2}] (R =s-C4H9,c-C6H11): Synthesis, structures, and13C and31P CP/MAS NMR spectra

✍ Scribed by M. A. Ivanov; V. V. Sharutin; A. V. Ivanov; A. V. Gerasimenko; O. N. Antsutkin


Book ID
111458200
Publisher
SP MAIK Nauka/Interperiodica
Year
2008
Tongue
English
Weight
381 KB
Volume
34
Category
Article
ISSN
1070-3284

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✍ Michael Schur; Wolfgang Bensch 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 German ⚖ 322 KB 👁 1 views

Reaction of elemental antimony with sulfur under mild hydrothermal conditions yielded different polysulfidoclusters of antimony. These were isolated as tetraphenylphosphonium salts [P(C 6 H 5 ) 4 ] 3 Sb 3 S 25 and [P(C 6 H 5 ) 4 ] 2 Sb 2 S 15 2(C 3 N 2 H 6 ) and their crystal structures were determi