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Tetramethylguanidine–silica nanoparticles as an efficient and reusable catalyst for the synthesis of cyclic propylene carbonate from carbon dioxide and propylene oxide

✍ Scribed by Adam, Farook; Batagarawa, Muazu Samaila


Book ID
120088666
Publisher
Elsevier Science
Year
2013
Tongue
English
Weight
947 KB
Volume
454
Category
Article
ISSN
0926-860X

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Supercritical carbon dioxide as solvent
✍ Donald J. Darensbourg; Nicole White Stafford; Takumi Katsurao 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 313 KB

Supercritical carbon dioxide was found to be a suitable substitute for halogenated organic solvents in its copolymerization with propylene oxide. The system was studied utilizing a heterogenous catalyst, zinc glutarate. The polymers were analyzed for selectivity in polycarbonate linkages by 'H NMR s