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Mixed-Linker Metal-Organic Frameworks as Catalysts for the Synthesis of Propylene Carbonate from Propylene Oxide and CO2

✍ Scribed by Wolfgang Kleist; Fabian Jutz; Marek Maciejewski; Alfons Baiker


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
874 KB
Volume
2009
Category
Article
ISSN
1434-1948

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DMAP/Cr(III) Catalyst Ratio: The Decisiv
✍ Robert Eberhardt; Markus Allmendinger; Bernhard Rieger πŸ“‚ Article πŸ“… 2003 πŸ› John Wiley and Sons 🌐 English βš– 68 KB

## Abstract Highly efficient formation of poly(propylene carbonate) can be achieved in the coupling of CO~2~ and propylene oxide assisted by 4‐(__N,N__‐dimethylamino)pyridine (DMAP) and catalyzed with salen chromium(III) chloride by using DMAP/Cr ratios of less than 2. Under these conditions a poss