Tetrakis(.beta.-diketonate)dimolybdenum complexes. Preparations, properties, and solid-state and molecular structure of tetrakis(2,2,6,6-tetramethyl-3,5-heptanedionato)dimolybdenum
✍ Scribed by Chisholm, Malcolm H.; Folting, Kirsten; Putilina, Elena F.
- Book ID
- 126116398
- Publisher
- American Chemical Society
- Year
- 1992
- Tongue
- English
- Weight
- 443 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0020-1669
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## Abstract Two neutral complexes [(L~6~^3^4M)Fe~2~Cl~4~]·2H~2~O·2CHCl~3~ (1) and [(L~6~^3^4M)Mn~2~Cl~4~]·CH~3~CN (2) have been synthesized {L~6~^3^4M = __N__,__N__,__N′__,__N′__‐tetrakis[(6‐methyl‐2‐pyridyl)methyl]propane‐1,3‐diamine} and their molecular structures established by X‐ray crystallogr
Reaction between 2,3,5,6-tetrakis(a-pyridyl)pyrazine (TPP) and the dimer , in which TPP behaves as a bis(bidentate) ligand between the two Pt atoms of the cation. Insertion of SnCl 2 into the Pt-Cl bonds of this compound led to an unusual rearranged product, (2), with a rare example of a pentacoor