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Preparation and solid-state structural, electronic, and magnetic properties of the 1,3,5-benzene-bridged tris(1,2,3,5-dithiadiazolyl)[1,3,5-C6H3(CN2S2)3]

✍ Scribed by Cordes, A. W.; Haddon, R. C.; Hicks, R. G.; Oakley, R. T.; Palstra, T. T. M.; Schneemeyer, L. F.; Waszczak, J. V.


Book ID
126021608
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
587 KB
Volume
114
Category
Article
ISSN
0002-7863

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(Benzene-1,3,5-triyl)tris[phosphine] (C6
✍ Stephanβ€…A. Reiter; Bernd Assmann; Stefanβ€…D. Nogai; Norbertβ€…W. Mitzel; Hubert Sch πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 German βš– 138 KB πŸ‘ 1 views

The prolonged photo-Arbuzov reaction (3 weeks, Hg lamp) of 1,3,5-trichloro-benzene with a large excess of trimethyl phosphite (as a solvent) at 508 gives moderate yields of dimethyl (3,5-dichlorophenyl)phosphonate (1; 14.5%), tetramethyl (5-chloro-1,3-phenylene)bis[phosphonate] (2; 35.4%), and hexam