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Tetrakis­(anilinium) hexa­chloro­tin(IV) dichloride

✍ Scribed by Rademeyer, Melanie


Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
156 KB
Volume
60
Category
Article
ISSN
1600-5368

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✦ Synopsis


The crystal structure of the double salt tetrakis(anilinium) hexachlorotin(IV) dichloride, (C 6 H 8 N) 4 [SnCl 6 ]Cl 2 , exhibits alternating inorganic and organic layers parallel to the ab plane. In the inorganic layer, ammonium groups interact with chloride anions and isolated tilted [SnCl 6 ] 2À octahedra through NÐHÁ Á ÁCl hydrogen bonds.


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The title compound, [Sn(C 6 H 3 Cl 2 ) 4 ], crystallizes in the monoclinic space group C2/c, with the molecules having no symmetry. In contrast, its isostere [3,5-(CH 3 ) 2 C 6 H 3 ] 4 Sn, (II), crystallizes in the tetragonal space group P421c.

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In the title coordination polymer, [Sn(C~2~H~5~)(C~6~H~5~)~2~(C~2~H~2~ClO~2~)]~__n__~, the five-coordinate Sn atom shows an SnC~3~O~2~ trigonal–bipyramidal geometry, with O atoms in the axial positions.