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Tetra­kis[4-(trifluoro­meth­yl)phen­yl]stannane

✍ Scribed by Young, David J. ;Manuaba, Putra ;Healy, Peter C. ;Tiekink, Edward R. T.


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
143 KB
Volume
61
Category
Article
ISSN
1600-5368

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Tetra­kis(4-fluoro­phen­yl)stannane
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The title compound, C 16 H 6 F 12 , has been obtained as a byproduct of the reaction between 2,5-bis(trifluoromethyl)phenyllithium and zinc(II) chloride. The asymmetric unit contains two independent molecules with a similar almost perpendicular conformation of the biphenyl fragments.

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The title compound, C~13~H~15~F~3~N~2~OS, shows an intramolecular N—H...O hydrogen bond and forms intermolecular N—H...S hydrogen bonds, generating a chain.

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In the title compound, C 12 H 14 F 3 N 3 O, the perhydropyridazine ring adopts a chair conformation. The amide group and the benzene ring are coplanar. Intermolecular N-HÁ Á ÁO hydrogen bonds link the molecules into a chain along the a axis.

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