𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Tetra­kis[(1-phenyl­tetra­zol-5-yl)sulfanylmethyl]methane

✍ Scribed by Lyakhov, Alexander S. ;Zatsepina, Marina V. ;Artamonova, Tatiana V. ;Gaponik, Pavel N. ;Koldobskii, Grigorii I.

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
370 KB
Volume
63
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

The title compound, C~33~H~28~N~16~S~4~, prepared by the divergent method, presents a core unit for further synthesis of tetrazole-containing dendrimers. The central C atom lies on a crystallographic twofold rotation axis. π–π Interactions and weak non-classical C—H...N hydrogen bonds are responsible for the formation of layers parallel to the bc plane, with van der Waals interactions between them.

📜 SIMILAR VOLUMES

1,2,4,5-Tetra­kis(bromo­meth­yl)benzene
1,2,4,5-Tetra­kis(bromo­meth­yl)benzene
✍ Wang, Zhi-Guo ;Wang, Yu-Zhou ;She, Neng-Fang ;Gao, Meng 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 114 KB

The title molecule, C 10 H 10 Br 4 , lies on a crystallographic inversion center which is located at the center of the benzene ring. The crystal structure is stabilized by intermolecular BrÁ Á ÁBr and C-HÁ Á ÁBr interactions.

Bis[2-(1-phen­yl-1H-tetra­zol-5-ylsulfan
Bis[2-(1-phen­yl-1H-tetra­zol-5-ylsulfan­yl)eth­oxy] ether
✍ Wang, Wei ;Zhao, Bing ;Zheng, Peng-Wu ;Duan, Xue-Min 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 92 KB

The title compound, C 20 H 22 N 8 O 2 S 2 , contains a center of inversion at the mid-point of the central C-C bond. The mean planes of the phenyl and the 1H-tetrazol-5-ylsulfanyl rings make a dihedral angle of 53.95 (16) .

1,6-Bis(1-methyl-1H-tetra­zol-5-ylsulfan
1,6-Bis(1-methyl-1H-tetra­zol-5-ylsulfan­yl)hexa­ne
✍ She, Jiang-Bo ;Zhang, Guo-Fang ;Dou, Yin-Li ;Fan, Xue-Zhong ;Li, Ji-Zhen 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 165 KB

The molecule of the title compound, C 10 H 18 N 8 S 2 , lies on a twofold rotation axis. Methyl C atoms contact N atoms of adjacent molecules through C-HÁ Á ÁN hydrogen bonds [3.445 (3) A ˚] in a molecular layer. In addition, the layers are linked by weak SÁ Á ÁS interactions [3.636 (3) A ˚].

1,4,8,11-Tetra­kis(carboxy­meth­yl)-5,5,
1,4,8,11-Tetra­kis(carboxy­meth­yl)-5,5,7,12,12,14-hexa­meth­yl-1,4,8,11-tetra­azoniacyclo­tetra­deca­ne tetra­chloride octa­hydrate
✍ Wang, Shi-Fan ;Li, Huan-Qiu ;Ruan, Ban-Feng ;Zhu, Hai-Liang ;Ng, Seik Weng 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 175 KB

The crystal structure of the centrosymmetric title compound, C 24 H 48 N 4 O 8 4+ Á4Cl À Á8H 2 O, consists of a 14-membered methylsubstituted C 10 N 4 cationic ring which interacts with the chloride ions and water molecules of crystallization to give a three-dimensional hydrogen-bonded network struc

(S)-N-(1H-Tetra­zol-5-ylmeth­yl)pyrrolid
(S)-N-(1H-Tetra­zol-5-ylmeth­yl)pyrrolidine-2-carboxamide dihydrate
✍ Zheng, Ji-Fu ;Zhang, Suo-Qin ;Wang, Li ;Yang, Song-Tao ;Li, Yao-Xian 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 153 KB

In the title compound, C 7 H 12 N 6 OÁ2H 2 O, all bond lengths and angles show normal values. The pyrrolidine ring adopts a C1-C -endo conformation. An extensive network of N-HÁ Á ÁO and O-HÁ Á ÁO hydrogen bonds stabilizes the crystal packing.