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Tetrahydrofuran in TiCl 4 /THF/MgCl 2 : a Non-Innocent Ligand for Supported Ziegler–Natta Polymerization Catalysts

✍ Scribed by Grau, Etienne; Lesage, Anne; Norsic, Sébastien; Copéret, Christophe; Monteil, Vincent; Sautet, Philippe

Book ID
127169356
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
745 KB
Volume
3
Category
Article
ISSN
2155-5435

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Morphological study of spherical MgCl2.n
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## Abstract Spherical MgCl~2~·nEtOH was prepared by adducting ethanol to MgCl~2~ using melt quenching method. Effect of molar ratio of [EtOH]/[MgCl~2~] = 2.8–3.05 on the morphology and particle size of the MgCl~2~·nEtOH were studied. The best adduct of spherical morphology was obtained when 2.9 mol

Synthesis of a TiCl4 Ziegler-Natta Catal
Synthesis of a TiCl4 Ziegler-Natta Catalyst Supported on Spherical MgCl2 · nEtOH for the Polymerization of Ethylene and Propylene
✍ Lidiane A. Almeida; Maria de Fátima V. Marques 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 661 KB

## Abstract Experiments designed to prepare Ziegler‐Natta catalysts with controlled particle morphology are reported. Different dealcoholation processes are used on the adduct MgCl~2~ · __n__EtOH to prepare the catalysts: either thermal treatment or chemical dealcoholation employing different subst