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Tetrahedra and Vertex-Sharing Double Tetrahedra in the Ammonium Iodomercurates(II) (NH4)7[HgI4]2 [Hg2I7](H2O) and (NH4)3[Hg2I7].

✍ Scribed by Peter Nockemann; Ingo Pantenburg; Gerd Meyer


Publisher
John Wiley and Sons
Year
2006
Weight
10 KB
Volume
37
Category
Article
ISSN
0931-7597

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✍ Jin Chen; Shao-Fang Lu; Zi-Xiang Huang; Rong-Min Yu; Qiang-Jin Wu πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons 🌐 English βš– 157 KB πŸ‘ 2 views

Reaction of [Mo 3 Y(m-S) 3 (dtp) 4 (H 2 O)] (Y O, S; dtp S 2 P(OC 2 H 5 ) 2 Γ€ ) with HgI 2 gave the novel compound {[Mo 3 S 7 (dtp) 3 ] 4 Β΄I}{(HgI 3 ) 3 } Β΄4 H 2 O (1), which contains a {[Mo 3 S 7 (dtp) 3 ] 4 Β΄I} tetramer and (HgI 3 ) Γ€ . Compound 1 has been characterized by IR, Raman, UV/Vis, and N