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Tetrahalometallates and metal sulphate salts of the 2,4-dimethyl-1H-1,5-benzodiazepinium cation

✍ Scribed by P.W.W. Hunter; G.A. Webb


Book ID
118909120
Publisher
Elsevier Science
Year
1972
Weight
391 KB
Volume
34
Category
Article
ISSN
0022-1902

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Reactions of 3,5-Diaryl-1,2-dithiolium S
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## Abstract Reaction of the 3,5‐diaryl‐1,2‐dithiolium salts 2 with the metal cyclopentadienides 4 and 9 leads to the formation of the tricyclic compounds 6 and 10 via a ring‐opened intermediate, which undergoes an intramolecular Diels‐Alder cyclization. Compounds 6 and 10 rearrange by treatment wit