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Tetracyclo[3.2.0.02,7.04,6]hept-1-ene: formation and trapping of 1,2-dehydroquadricyclane. Ab initio calculations on dehydroquadricyclanes

✍ Scribed by Podlech, Joachim; Polborn, Kurt; Szeimies, Guenter


Book ID
124151998
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
632 KB
Volume
58
Category
Article
ISSN
0022-3263

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## Abstract Reaction of bromotrichlorohomocubane 8 with MeLi in the presence of anthracene, 9,10‐dimethoxyanthracene, 1,2,3‐tri‐methylisoindole, diphenylisobenzofuran, and 2,5‐dimethyl‐furan furnished Diels‐Alder adducts of the title compound 2,5‐dichlorohomocubene 7 in reasonable yields. Adduct 14