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Base-promoted eliminative cyclization: Novel synthesis of functionalized tetracyclo[6.2.1.02,7.04,10]Undecane and tetracyclo[5.3.0.02,6.05,9]Decane systems

โœ Scribed by Chandler Suri Suresh


Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
253 KB
Volume
31
Category
Article
ISSN
0040-4039

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A novel entry into 3-bromo-7-(bromomethyt)tetracyclo[5.3.1.02"6.04"S]undec~10(12)-ene-9,11-dione, which readily undergoes further rearrangement with primary amines, has been developed through photolysis of 2,5bis(bromomethyl)tricyelo[6.2.1.02"7]undec-4,9-diene-3,6-dione.