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Tetracyclic systems: Synthesis of isoindolo[1,2-b]thieno-[2,3(3,2 or 3,4)-e][1,3]thiazocines and Isoindolo[2,1-a]thieno-[2,3(3,2 or 3,4)-f][1,4] and [1,5]diazocines

✍ Scribed by Pascal Pigeon; Bernard Decroix


Publisher
Journal of Heterocyclic Chemistry
Year
1997
Tongue
English
Weight
432 KB
Volume
34
Category
Article
ISSN
0022-152X

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✦ Synopsis


Abstract

Cyclization of thioglycolic acids derivatives 3a‐d gave isoindolo[1,2‐b]thieno[2,3(3,2 or 3,4)‐e][1,3]‐thiazocines 4a‐d. Isoindolo[2,1‐a]thieno[2,3(3,2 or 3,4)‐f][1,4] or [1,5]diazocines 10b or 11a‐c were synthesized from Beckmann or Schmidt rearrangement of the ketones 7a‐c.


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