In the centrosymmetric title compound, [Cd(C 6 H 5 N 2 O 4 ) 2 -(H 2 O) 4 ], the Cd II cation is coordinated by two uracil-1-acetate anions via carboxylate O atoms, and four water molecules, forming a six-coordinate octahedral environment. O-HÁ Á ÁO and N-HÁ Á ÁO hydrogen-bonding interactions link a
Tetraaquabis(5-fluorouracil-1-acetato)manganese(II)
✍ Scribed by Hu, Mao-Lin
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 184 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the centrosymmetric title compound, [Mn(C 6 H 4 N 2 O 4 F) 2 -(H 2 O) 4 ], each Mn II ion is coordinated by two 5-fluorouracil-1acetate anions via the carboxylate O atoms and four water molecules, forming a six-coordinate octahedral environment. N-HÁ Á ÁO and O-HÁ Á ÁO hydrogen-bonding interactions link adjacent molecules into a three-dimensional network.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.008 A Ê R factor = 0.055 wR factor = 0.161 Data-to-parameter ratio = 12.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 163 K Mean '(C±C) = 0.007 A Ê Disorder in main residue R factor = 0.039 wR factor = 0.109 Data-to-parameter ratio = 12.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.