In the title complex, [Cd(NO~3~)~2~(C~20~H~14~N~4~)~2~]·2H~2~O, the Cd^II^ ion, which lies on a crystallographic twofold axis, is bis-chelated by two nitrate ligands and is coordinated by one tertiary N atom from each of two 1,3-bis(1__H__-benzimidazol-2-ylmethyl)benzene ligands in a distorted octah
✦ LIBER ✦
Tetraaquabis[1-(carboxylatomethyl)-1,3-benzimidazol-3-ium-3-acetato-κO]manganese(II) dihydrate
✍ Scribed by Huang, Ling ;Chen, Ding-Ben
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 217 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
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We gratefully acknowledge the financial support of the Natural Science Foundation of China (No. 20573114).
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The dicarboxylate ligand in the title compound, [Mn(C 9 H 6 -O 5 )(C 12 H 8 N 2 ) 2 (H 2 O)]Á4H 2 O, coordinates in a monodentate manner to the Mn II atom through the carboxylate group on the benzene ring. The two O atoms in the octahedral configuration around the Mn II atom are cis to each other. E