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Tetra-μ-carboxylato-rhodium(II)-rhodium(III) perchlorate

✍ Scribed by Monika Moszner; Józef J. Ziółkowski


Publisher
Springer
Year
1982
Tongue
English
Weight
158 KB
Volume
7
Category
Article
ISSN
0340-4285

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Tri-μ-chloro-bis­[(η5-penta­methyl­cyclo
✍ Liu, Lihua ;Zhang, Qian-Feng ;Leung, Wa-Hung 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 167 KB

In the cation of the title compound, [Rh 2 Cl 3 (C 10 H 15 ) 2 ]BF 4 , two Rh( 5 -C 5 Me 5 ) fragments are linked by three bridging Cl atoms. Each rhodium center has a pseudo-octahedral coordination geometry, with a C 5 Me 5 group occupying three positions and three Cl atoms completing the coordinat