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Tetra-(tetraalkylammonium)octamolybdate catalysts for selective oxidation of sulfides to sulfoxides with hydrogen peroxide

โœ Scribed by Yang, Chuanbo; Jin, Qingping; Zhang, Hua; Liao, Jian; Zhu, Jin; Yu, Bin; Deng, Jingen

Book ID
111879646
Publisher
Royal Society of Chemistry
Year
2009
Tongue
English
Weight
129 KB
Volume
11
Category
Article
ISSN
1463-9262

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TMSCl-promoted selective oxidation of su
TMSCl-promoted selective oxidation of sulfides to sulfoxides with hydrogen peroxide
โœ Kiumars Bahrami; Mohammad M. Khodaei; Behrooz H. Yousefi; Mehdi Sheikh Arabi ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 584 KB

Selective oxidation of sulfides to sulfoxides is achieved using H 2 O 2 and TMSCl as the promotor. Aromatic and aliphatic sulfides are oxidized to sulfoxides in excellent yields and in short reaction times. Different functional groups including ketone, alkene, ester, and alcohol are tolerated.