Constants of the rawions of Cl with HIOz. IX&, 03, CH4, and HNC)J wertt mezxured at 295 K using a flaw discharge-mass spectrometric method. The rate consmts are, WpectiveIy, (6.2 ?c I.51 X 10qzS, (32&) x 10"tl, (1.3 -+. 0.3) X lo-'t, (1.2 ?t 0.3) X 10-13, and (6.8 t 3.4) X lO-is cm3/s.
Tests of stratospheric models: The reactions of atomic chlorine with O 3 and CH 4 at low temperature
β Scribed by DeMore, W. B.
- Book ID
- 119684799
- Publisher
- American Geophysical Union
- Year
- 1991
- Tongue
- English
- Weight
- 473 KB
- Volume
- 96
- Category
- Article
- ISSN
- 0148-0227
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## Abstract The theoretical investigations were performed on the reaction mechanisms for the title reactions CH~3~C(O)CH~3~ + Cl β products (R1), CH~3~C(O)CH~2~Cl + Cl β products (R2), CH~3~C(O)CHCl~2~ + Cl β products (R3), and CH~3~C(O)CCl~3~ + Cl β products (R4) by __ab initio__ direct dynamics a