Tertiary phosphine complexes of nickel, palladium, platinum, cobalt and zinc: a spectroscopic study

✍ Scribed by J.E. Fergusson; P.F. Heveldt

• Book ID: 104137649
• Publisher: Elsevier Science
• Year: 1978
• Tongue: English
• Weight: 816 KB
• Volume: 31
• Category: Article
• ISSN: 0020-1693
• DOI: 10.1016/s0020-1693(00)94992-2

✦ Synopsis

X and L as above, have been prepared and their low frequency infrared and 'H, 13C and 31P nuclear magnetic resonance spectra have been recorded. Trends in the v(M-X), v(M-P) and G(MPC) vibration modes and in the chemical shift of the methylene group of the phosphines have been related to electronic effects within the complexes which influence the metal-ligand bond. New assignments of the vibrational modes v(M-P) and G(MPC) have been given.