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Tertiary Amine Catalysis of The Aldol Condensation

โœ Scribed by Gutsche, C. David.; Buriks, Rudolf S.; Nowotny, Kurt.; Grassner, Hans.


Book ID
118236706
Publisher
American Chemical Society
Year
1962
Tongue
English
Weight
377 KB
Volume
84
Category
Article
ISSN
0002-7863

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Stereochemical control of tertiary alcoh
โœ Tomoyuki Kamino; Yoshihisa Murata; Nobuyuki Kawai; Seijiro Hosokawa; Susumu Koba ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 71 KB

Stereoselective construction of aldol adducts having tertiary alcohol at the a position was achieved via a titanium(IV) enolate derived from a lactate derivative with an Evans chiral auxiliary. The stereochemistry at a-tertiary alcohol could be controlled by selecting the protective group of the sta