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Tertiary Amide Rotation in a Nanoscale Host

✍ Scribed by Riccardo Salvio; Lionel Moisan; Dariush Ajami; Julius Rebek Jr.


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
195 KB
Volume
2007
Category
Article
ISSN
1434-193X

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Stereodynamics of bond rotation in terti
✍ Pablo Campomanes; M. Isabel Menéndez; Ramón López; Tomás L. Sordo 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 300 KB

## Abstract Computations sho that independent NCO rotation is not possible in __N,N‐__diethyl‐1‐naphthamide, and that the coalescence signal corresponding to methyl equivalence observed in the VT NMR spectrum of this system is caused by a complex process whose rate‐determining step implies concert