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Correlated rotation in a conformationally restricted amide

✍ Scribed by Eric R. Johnston; Robin Fortt; James C. Barborak


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
882 KB
Volume
38
Category
Article
ISSN
0749-1581

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The rotational barriers in bis(2,4,Ctri-tert-butylphenyl) diselenide and ditelluride have been investigated by total line-shape analysis of variabletemperature 'H NMR spectra in CFCI,-CD,CI, (85: 15). The free energies of activation, AGf,,, K, for the diselenide and ditelluride were determined to be