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tert -Butylation of Phenol over Ordered Solid Acid Catalysts in Supercritical Carbon Dioxide: Efficient Synthesis of 2,4-Di- tert -butylphenol and 2,4,6-Tri- tert -butylphenol

✍ Scribed by Kamalakar, Gunda; Komura, Kenichi; Sugi, Yoshihiro


Book ID
127287757
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
161 KB
Volume
45
Category
Article
ISSN
0888-5885

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Radical pairs are formed by photolysis of single crystals of 2,6-di-tert-butyl-4-methylphenol (ionol) (1) or 2,6-di-tert-butylphenol (2 ), doped by several different molecules, and investigated by the EPR method. A possible two-hydrogen-atom transfer is discussed as the photochemical act.