The title compound, C 8 H 19 OP, is the oxidation product of t Bu 2 PH. The molecule is located on a crystallographic mirror plane. As a result, there is just one half-molecule in the asymmetric unit.
tert-Butylamidodichlorophosphine oxide
✍ Scribed by Chivers, Tristram ;Grebinski, James ;Parvez, Masood ;Fu, Zhiyong
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 194 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
The monomeric units in the title compound, C 4 H 10 Cl 2 NOP, are linked together by N-HÁ Á ÁO hydrogen bonds to give parallel linear strands along the b axis.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.008 A Ê R factor = 0.039 wR factor = 0.142 Data-to-parameter ratio = 15.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, [PtCl~2~(C~8~H~19~P)(C~18~H~15~P)]·0.5C~4~H~8~O, was obtained in the reaction of bis(triphenylphosphine)platinum(II) chloride with 1,1,3,3-tetra-__tert__-butyl-2-trimethylsilyltriphosphine. The ^31^P{^1^H} NMR spectrum of the reaction mixture shows the formation of the title comp