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(tert-Butyl isocyanide)chlorogold(I)

โœ Scribed by Eggleston, D. S. ;Chodosh, D. F. ;Webb, R. L. ;Davis, L. L.


Book ID
114503999
Publisher
International Union of Crystallography
Year
1986
Tongue
English
Weight
327 KB
Volume
42
Category
Article
ISSN
0108-2701

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The title compound, [Mo(C 5 H 9 N) 3 (CO) 3 ], was produced from Mo(CO) 6 and tert-butyl isocyanide in the presence of 10 atm of carbon monoxide (1 atm = 101325 Pa). The octahedral complex shows a facial arrangement of the ligands, the Mo-C distances of the isocyanide ligands being about 0.15 A หšlon

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