The title compound, [Cu(C 5 H 9 N) 4 ]ClรH 2 O, was obtained from the reaction of copper(II) chloride hydrate with KCN in the presence of two equivalents of tert-butylisocyanide. The reaction proceeds via the reduction of copper and the formation of (CN) 2 . The compound shows a tetrahedrally surrou
โฆ LIBER โฆ
(tert-Butyl isocyanide)chlorogold(I)
โ Scribed by Eggleston, D. S. ;Chodosh, D. F. ;Webb, R. L. ;Davis, L. L.
- Book ID
- 114503999
- Publisher
- International Union of Crystallography
- Year
- 1986
- Tongue
- English
- Weight
- 327 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0108-2701
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Tetraยญkis(tert-butyl isocyanide)copper(I
โ
Imhof, Wolfgang ;Halbauer, Kathi ;Gรถrls, Helmar
๐
Article
๐
2005
๐
International Union of Crystallography
๐
English
โ 282 KB
Bis(tert-butyl isocyanide)hexadecacarbon
โ
Orpen, A. G. ;Sheldrick, G. M.
๐
Article
๐
1978
๐
International Union of Crystallography
โ 338 KB
fac-Tris(tert-butyl isocyanide)tricarbon
โ
Imhof, Wolfgang ;Halbauer, Kathi ;Dรถnnecke, Daniel ;Gรถrls, Helmar
๐
Article
๐
2006
๐
International Union of Crystallography
๐
English
โ 182 KB
The title compound, [Mo(C 5 H 9 N) 3 (CO) 3 ], was produced from Mo(CO) 6 and tert-butyl isocyanide in the presence of 10 atm of carbon monoxide (1 atm = 101325 Pa). The octahedral complex shows a facial arrangement of the ligands, the Mo-C distances of the isocyanide ligands being about 0.15 A หlon
tert-Butoxycopper-carbonyl and tert-buto
โ
Tsuda, Tetsuo; Habu, Haruo; Horiguchi, Sadashige; Saegusa, Takeo
๐
Article
๐
1974
๐
American Chemical Society
๐
English
โ 280 KB
Synthesis and structure of hexakis(tert-
โ
Silverman, Lance D.; Corfield, Peter W. R.; Lippard, Stephen J.
๐
Article
๐
1981
๐
American Chemical Society
๐
English
โ 523 KB
Higher coordinate cyanide and isocyanide
โ
Dewan, John C.; Giandomenico, Christen M.; Lippard, Stephen J.
๐
Article
๐
1981
๐
American Chemical Society
๐
English
โ 831 KB