Termination of manganese(III)-based oxidative free-radical cyclizations by addition to nitriles. Formation of cyclopentanones and cyclohexanones
β Scribed by Snider, Barry B.; Buckman, Brad O.
- Book ID
- 127357830
- Publisher
- American Chemical Society
- Year
- 1992
- Tongue
- English
- Weight
- 718 KB
- Volume
- 57
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
Oxidative free radical cyclizations of 8-ketoesters 1,5, II, and 14 with Mn(OAc)s\*2H20 and Cu(OAc)z\*HaO proceed in moderate yield to give seven-and eight-membered rings. The regiochemistry of the cyclization and oxidative termination are described. We have recently described manganese (III)-based
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