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Temporary in Situ Aluminum and Zinc Tethering in Diels−Alder Reactions

✍ Scribed by Bertozzi, Fabio; Olsson, Roger; Frejd, Torbjörn

Book ID
120824562
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
81 KB
Volume
2
Category
Article
ISSN
1523-7060

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Dienes readily undergo Diels-Alder reaction with CH 2 C(NO 2 )SO 2 Ph (2a), CH 2 C(NO 2 )CO 2 Et (2b), and CH 2 C(NO 2 )COPh (2c), all observed in situ by 1 H NMR. The cycloadducts of 2a undergo S RN 1 reactions.