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Notes. Generation of Nitroethylene in Situ for Use in Diels-Alder Reactions

✍ Scribed by Kaplan, Ralph; Shechter, Harold

Book ID
126301030
Publisher
American Chemical Society
Year
1961
Tongue
English
Weight
265 KB
Volume
26
Category
Article
ISSN
0022-3263

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Generation and in situ Diels–Alder react
Generation and in situ Diels–Alder reactions of activated nitroethylene derivatives
✍ Peter A. Wade; James K. Murray Jr.; Sharmila Shah-Patel; Patrick J. Carroll πŸ“‚ Article πŸ“… 2002 πŸ› Elsevier Science 🌐 French βš– 116 KB

Dienes readily undergo Diels-Alder reaction with CH 2 C(NO 2 )SO 2 Ph (2a), CH 2 C(NO 2 )CO 2 Et (2b), and CH 2 C(NO 2 )COPh (2c), all observed in situ by 1 H NMR. The cycloadducts of 2a undergo S RN 1 reactions.