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Templatsynthese von [CuII2CuI3K6(μ6-Cl)(μ3-OtBu)12] und theoretische Untersuchung des ersten gemischtvalenten Kupferalkoxids

✍ Scribed by Reinhart Ahlrichs; Christopher E. Anson; Dieter Fenske; Oliver Hampe; Alexander Rothenberger; Marek Sierka


Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
131 KB
Volume
115
Category
Article
ISSN
0044-8249

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Template Synthesis and Theoretical Inves
✍ Reinhart Ahlrichs; Christopher E. Anson; Dieter Fenske; Oliver Hampe; Alexander 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 131 KB

In recent years we have investigated the syntheses, structures, and properties of a variety of copper-chalcogen clusters. [1] The general synthetic route to these species involves the reaction of CuX (X = halide, carboxylate) salts with tertiary phosphanes and subsequent reaction with trimethylsilyl