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Template Synthesis of Ruthenium Complexes with Saturated and Benzannulated NH,NH-Stabilized N-Heterocyclic Carbene Ligands

✍ Scribed by Kaufhold, Oliver; Flores-Figueroa, Aarón; Pape, Tania; Hahn, F. Ekkehardt

Book ID
120495963
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
195 KB
Volume
28
Category
Article
ISSN
0276-7333

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## Abstract The reaction of 2‐azidophenyl isocyanide (**7**) with [M(CO)~5~(thf)] (M=Cr, W) yields the isocyanide complexes [M(CO)~5~(**7**)] (M=Cr **8**, M=W **9**). Complexes **8** and **9** react with tertiary phosphines such as triphenylphosphane at the azido function of the isocyanide ligand t