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Synthesis of Benzannulated N-Heterocyclic Carbene Ligands by a Template Synthesis from 2-Nitrophenyl Isocyanide

✍ Scribed by F. Ekkehardt Hahn; César García Plumed; Marco Münder; Thomas Lügger


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
336 KB
Volume
10
Category
Article
ISSN
0947-6539

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## Abstract The reaction of 2‐azidophenyl isocyanide (**7**) with [M(CO)~5~(thf)] (M=Cr, W) yields the isocyanide complexes [M(CO)~5~(**7**)] (M=Cr **8**, M=W **9**). Complexes **8** and **9** react with tertiary phosphines such as triphenylphosphane at the azido function of the isocyanide ligand t