Template Synthesis of Benzannulated N-He
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F. Ekkehardt Hahn; Volker Langenhahn; Nicole Meier; Thomas Lügger; Wolf Peter Fe
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Article
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2003
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John Wiley and Sons
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English
⚖ 285 KB
👁 1 views
## Abstract The reaction of 2‐azidophenyl isocyanide (**7**) with [M(CO)~5~(thf)] (M=Cr, W) yields the isocyanide complexes [M(CO)~5~(**7**)] (M=Cr **8**, M=W **9**). Complexes **8** and **9** react with tertiary phosphines such as triphenylphosphane at the azido function of the isocyanide ligand t