Template Synthesis of Clusters using the Tripod Ligand HC(PPh2)3 Ni3(CO)6(tripod)
β Scribed by Prof. J. A. Osborn; Dr. George G. Stanley
- Publisher
- John Wiley and Sons
- Year
- 1980
- Tongue
- English
- Weight
- 234 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract Reaction of [Ni~6~(CO)~12~]^2β^ in thf with 2 equiv. of the softLewis acid CdCl~2~Β·2.5H~2~O gives the new dimeric species {Cd~2~Cl~3~[Ni~6~(CO)~12~]~2~}^3β^. The formation of the latter is not the result of direct addition of CdCl~2~ to [Ni~6~(CO)~12~]^2β^, but it involves some intermed
The hexacarbide clusters [H 6-n Ni 38 C 6 (CO) 42 ] n-(n = 3, 4, 5, found previously in [HNi 38 C 6 (CO) 42 ] 5-, and shows very close interatomic separations. Both [Ni 32 C 6 (CO) 36 ] 6-and [H 6- or 6) have been directly obtained from the reaction of [Ni 6 -(CO) 12 ] 2-with C 3 Cl 6 , whereas the