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N2Hx Coordination at the Tripod-Cobalt Template CH3C(CH2PPh2)3Co: the Transformation of η2-HNNMe2 into η1-NNMe2Ligands

✍ Scribed by Körner, Volkmar ;Huttner, Gottfried ;Vogel, Sabine ;Barth, Annette ;Zsolnai, Laszlo

Publisher
Wiley (John Wiley & Sons)
Year
1997
Tongue
English
Weight
379 KB
Volume
130
Category
Article
ISSN
0009-2940

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## Abstract Thermolysis of Ru(IMes)(dppp)(CO)H~2~ (1, IMes=1,3‐dimesityl‐1,3‐dihydro‐2__H__‐imidazol‐2‐ylidene; dppp=Ph~2~PCH~2~CH~2~CH~2~PPh~2~) in the presence of trimethylvinylsilane yields Ru(IMes')(dppp)(CO)H (2) resulting from intramolecular ArCH~2~–H CH bond activation of the __N__‐heterocy