𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Template Synthesis and Structure of a Three-Dimensional Bimetallic Phosphate

✍ Scribed by Yongnan Zhao; Jing Ju; Xiangming Chen; Xiuhong Li; Yong Wang; Ruji Wang; Ming Li; Zhenhong Mai

Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
348 KB
Volume
166
Category
Article
ISSN
0022-4596

No coin nor oath required. For personal study only.

✦ Synopsis

Introducing cobalt into the Zn-P-O-amine system and using oxalates as starting materials, an amine-containing openframework zinc cobalt phosphate, [C 2 N 2 H 10 ][Co 4.2 Zn 1.8 (PO 4 ) 4 (HPO 4 )] . H 2 O (1), has been hydrothermally synthesized. It crystallizes in monoclinic space group C2=c (No. 15) with cell parameters a ¼ 19:214ð8Þ

The structure contains two sets of M-O-M linkage: M-O-M dimer and unusual infinite helical -M-O-M-chain. Connecting the dimers by phosphates leads to three-membered ring chains. The linking of the helical chains by PO 4 groups results in a sheet structure. Using the three-membered ring chains as pillars, stacking of the sheets gives rise to a three-dimensional tunnel structure. # 2002 Elsevier Science (USA)

📜 SIMILAR VOLUMES

ChemInform Abstract: Synthesis and Struc
ChemInform Abstract: Synthesis and Structural Characterization of Two- and Three- Dimensional Fluorinated Indium Phosphates.
✍ H. DU; J. CHEN; W. PANG; J. YU; I. D. WILLIAMS 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 27 KB 👁 2 views

Synthesis and Structural Characterization of Two-and Three-Dimensional Fluorinated Indium Phosphates. -Two novel fluorinated indium phosphates, (InPO4F(Hen)) (I) and ( In5P4F3O16(H2O)2(en)3) (II) are prepared hydrothermally using ethylene diamine as templating agent in a fluoride-containing system.

Hydrothermal synthesis and crystal struc
Hydrothermal synthesis and crystal structure of a three-dimensional polyoxovanadate
✍ Huiyuan Ma; Xiaodan Wang; Baoxia Dong; Chunxiang Li; Lizhou Wu 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 234 KB 👁 2 views

## Abstract A three‐dimensional polyoxovanadate formulated as HV~3~O~8~·H~2~O has been synthesized by hydrothermal method. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

Synthesis of Large-Area Three-Dimensiona
Synthesis of Large-Area Three-Dimensional Polyaniline Nanowire Networks Using a “Soft Template”
✍ Wenbin Zhong; Jianyuan Deng; Yongsheng Yang; Wantai Yang 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 305 KB

## Abstract **Summary:** Three‐dimensional polyaniline (PANI) nanowire networks were synthesized in high yield using a “soft template” self‐assembled with hexadecyltrimethylammonium bromide and oxalic acid. The PANI nanowire networks had diameters from 35–100 nm depending on synthesis conditions an