Template Cooperation Effect Leading to the New Layered Aluminophosphate CN 3 H 6 ·Al(HPO 4 ) 2 ·2H 2 O
✍ Scribed by Bircsak, Zsolt; Harrison, William T. A.
- Book ID
- 126005095
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 192 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0897-4756
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The solution-phase synthesis, single crystal structure, and some physical properties of CN 3 H 6 • VO(H 2 O)(HPO 4 ) (H 2 PO 4 ) • H 2 O, a new guanidinium vanadium (IV) hydrogen phosphate hydrate, are reported. This phase is built up from one-dimensional chains of VO 5 (H 2 O) octahedra and (H 2 /H
The first example of an aluminophosphate containing organic anions covalently bonded to the framework of the structure is reported was prepared hydrothermally and adopts a layered structure. The oxalate groups act as bidentate ligands to Al 3؉ and hold the structure together by strong interlayer P-