Temperature, solvent, and substituent effects on the singlet oxidations of allylic phenyl sulfoxides, sulfones, and sulfides
β Scribed by Clennan, Edward L.; Chen, Xiangning
- Book ID
- 126258370
- Publisher
- American Chemical Society
- Year
- 1989
- Tongue
- English
- Weight
- 862 KB
- Volume
- 111
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
## Abstract ^13^CβNMR. and He (IΞ±) photoelectron spectra of alkyl phenyl sulfides, sulfoxides and sulfones have been used to probe how their conformations depend on the size of the alkyl groups R. The results are interpreted to indicate that in the sulfides the S, Rβbond is twisted out of the plana
The reaction of 3-hydroperoxy-4,4,5,5-tetramethyl-3phenyl-1,2-dioxolane, 1, with a series of sulfides (2a β«Χ‘β¬ thioanisole, 2b β«Χ‘β¬ ethyl phenyl sulfide, 2c β«Χ‘β¬ 2-chloroethyl phenyl sulfide, and 2d β«Χ‘β¬ 2-chloroethyl methyl sulfide) at 34ΠC in various solvents yielded the corresponding sulfoxides and 3