Temperature induced symmetry transformation in the Th3P4 type compounds La3S4, La3Se4, Pr3S4 and Pr3Se4
β Scribed by P.D. Dernier; E. Bucher; L.D. Longinotti
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 327 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0022-4596
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π SIMILAR VOLUMES
Ruby-red, bead-shaped single crystals of C-type La 2 Se 3 (a = 905.21(6) pm), Pr 2 Se 3 (a = 891.17(6) pm), and Gd 2 Se 3 (a = 872.56(5) pm) are obtained by oxidation of the respective rare-earth metal (M = La, Pr and Gd) with selenium (molar ratio 2 : 3) in evacuated silica tubes at 750 Β°C in the p
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